Clean up affected area. Discard any contents after use in . Show this material safety data sheet to the doctor in attendance. worth. Take up dry. P308+P313 IF exposed or concerned: Get medical advice/attention. A solution of aluminium chloride and its hydrates. Please use the navigational links to explore our website. To dispose of these chemicals, place the containers in a box lined with a plastic bag, tape the top of the box shut, write "Normal Trash" on the box and then place the box next to the lab trash container. Why does Calcium Chloride get put in these tractor tires anyway? According to the Code of Federal Regulations, desiccant is a non-combustible waste, unless it is lime-based. Feeling tired or weak. If so, what did you do with the leftover product after using it? wikiHow, Inc. is the copyright holder of this image under U.S. and international copyright laws. We are the only oilfield service provider to manufacture our own calcium chloride and heavy brines, ensuring consistent quality and security of supply for our customers. Check before you dump chemicals into the ground. The older fellas know some tricky ways to rid themselves of over abundance of fluids that many might consider harmful. Our food-grade calcium chloride products are 100% water-soluble which presents an advantage over less soluble calcium solutions such as gypsum and limestone. wikiHow, Inc. is the copyright holder of this image under U.S. and international copyright laws. Store the closed containers in a dry area to prevent the CaCl2 from liquefying. "height": 57 National Center for Biotechnology Information. website: https://www.epa.govt.nz/, United States Toxic Substances Control Act (TSCA) Inventory:Listed. Product Name Calcium chloride. Calcium chloride prills. Call in ophthalmologist. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? In Iowa it is legal to put on gravel roads to suppress dust, but this may not be true in your area. 233-140-8 Molecular Formula Ca Cl2 Reach Registration Number -1.2. For example, do a search like liquid calcium chloride disposal Illinois. You could also contact your local water or sanitation department directly. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. ts the most powerful of the common de-icers, used for. "image": { Check before you dump chemicals into the ground. The molecular mass or weight of the chemical is 110.98g. wikiHow, Inc. is the copyright holder of this image under U.S. and international copyright laws. The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. It may be necessary to contain and dispose of Calcium Carbide as a HAZARDOUS WASTE. If you are overseas, however, you will need to check with that country's regulatory authorities for proper disposal. Contact Supplier Request a quote. If a large amount of calcium chloride is consumed, drink several glasses of water or milk and seek medical attention as needed, according to the IPCS. Boiling and Melting Points of Calcium Chloride. RAILROAD RITE-of-way . The methods for determining the biological degradability are not applicable to inorganic substances. Apart from the uses mentioned in section 1.2 no other specific uses are stipulated, Use equipment for eye protection tested and approved under appropriate, government standards such as NIOSH (US) or EN 166(EU). Chemicals, like other types of waste, can be harmful to human health or to the environment, either immediately or over an extended period of time. Yes water freezes but it if a lot heavier than water, with water you would also need a steel weight to equal the weight of calcium, I need some and hard to find, Thanks Scrub & Leroy. It is a salt that is solid at room temperature, and it behaves as a typical ionic halide. Simply dispose of the desiccant with your normal trash. Minimum layer thickness: 0,11 mm Break through time: 480 min. "R}~Q:~pgg'"l/O:OV~
@zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#bXu`^D23uOxT4D~PD<.O3@MG({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>NrZt^Vu1|)3IFovp,L~a*?|"z/Ow`/^ 6. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Materials that will not burn in air when exposed to a temperature of 820 C (1,500 F) for a period of 5 minutes.(e.g. stream
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. I had probably 2-3 grams of calcium hydride leftover in a schlenk flask from predrying a distillation of benzyl chloride. Hazardous wastes, including chemical waste, fall into one of three broad . It is a deliquescent salt, meaning it can liquefy by absorbing moisture in the air. "description":"Discussion of Calcium chloride disposal in the Ford 9N, 2N & 8N forum followed by comments. We use some essential cookies to make this website work. TETRA calcium chloride fits a large range of industrial applications including water treatment, pulp and paper, concrete acceleration, polymer manufacturing, humidity absorption, and mining industry applications. bromine trifluoride. All I have ever heard of is just plain old water. Additionally, calcium chloride can cause corrosion when it comes into contact with metal. One of those ways is: Take a 5 gal. Dike far ahead of liquid spill for later disposal. "name": "Teakettle" If you get CaCl2 in your eye, flush it with water for at least 15 minutes, then see an eye doctor. 10 mL, calcium chloride 10% (providing approximately 6.8 mmol of calcium) should be administered as a single dose, repeat dose if no improvement in ECG within 5 to 10 minutes. "headline":"Calcium chloride disposal", In many areas, you can dispose of CaCl2 in the regular trash if its solid, or by washing it down the drain if its in liquid form. }, Is the extra weight that important? Additionally, calcium chloride can be used to make concrete more durable. Calcium chloride MSDS - 102379 - Merck. Show this material safety data sheet to the doctor in attendance. "@type":"DiscussionForumPosting", This image is not<\/b> licensed under the Creative Commons license applied to text content and some other images posted to the wikiHow website. It has several common applications such as brine for refrigeration plants, ice and dust control on roads, and in cement. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. "@type": "Organization", endobj
Keeps unwanted moisture and condensation under control, protects against musty odours and mildew. In 2017, she graduated with her PhD in Egyptology from The University of Chicago, where she served for several years as a content advisor and program facilitator for the Oriental Institute Museums Public Education office. <<
See www.retrologistik.com for processes regarding the return of chemicals and. At last,Calcium chloride(10043-52-4) safety, risk . Calcium oxide, Methyl vinyl ether, note: Calcium chloride is attacked by . You can obtain more information on identifying hazardous waste and the Hazardous Waste Regulations from the Environment Agency website. "url": "https://www.yesterdaystractors.com/graphics/smllogo.png", The calcium oxide in lime generates heat when in contact with water. %PDF-1.4
Calcium chloride is made up of calcium and chlorine and belongs to the salt family of elements. Throw away the used desiccant if you prefer not to use it again. Check benefits and financial support you can get, Find out about the Energy Bills Support Scheme, Apply for special collection of large waste items. You can reuse the desiccant at another time and continue reuse it by reheating in a microwave. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. The handeling/disposal issues to me outweighs the benefit. Test Type: Mutagenicity (mammal cell test): chromosome aberration. All I have ever heard of is just plain old water. You will find Calcium Chloride in pickles, beer, and cheese making as well as in some bottled waters you buy at the store. Get the idea? Keep Food Tasting and Looking Good. Price (UOM) Price (Package) Calcium Chloride 94-97%, mini pellets - Technical Grade - 50 lb Bag. {"smallUrl":"https:\/\/www.wikihow.com\/images\/thumb\/e\/e4\/Dispose-of-Calcium-Chloride-Step-1-Version-2.jpg\/v4-460px-Dispose-of-Calcium-Chloride-Step-1-Version-2.jpg","bigUrl":"\/images\/thumb\/e\/e4\/Dispose-of-Calcium-Chloride-Step-1-Version-2.jpg\/aid11783177-v4-728px-Dispose-of-Calcium-Chloride-Step-1-Version-2.jpg","smallWidth":460,"smallHeight":345,"bigWidth":728,"bigHeight":546,"licensing":" \u00a9 2023 wikiHow, Inc. All rights reserved. Product Description: Calcium chloride Cat No. Calcium Chloride, Laboratory Chemical Grade 5 Items. Ingestion can cause nausea, vomiting or gastric distress. On the upper Texas Gulf Coast. As a solid, calcium chloride is hygroscopic (absorbs water) but also exothermic (releases heat) when it touches water. If necessary, use trained response staff/contractor.Dust deposits should not be allowed to accumulate on . containers, or contact us there if you have further questions. If your work is likely to stir up a lot of dust, wear a ventilator mask with a particulate filter to help prevent inhalation. The container is all swollen and the date on the bottle is Dec 1988. Product identifier Product name CALCIUM CHLORIDE Product number 260 Synonyms; trade names CALCIUM (II) CHLORIDE,CALCIUM DICHLORIDE,WATER HARDENER,CALC CHLORIDE,BRISWIM WATER HARDENER,CALCIUM CHLORIDE 0AQ FCC ED 7,CALCIUM CHLORIDE 95/98% Calcium carbonate is soluble in concentrated mineral acids. If inhaled. And It'll keep you from slippin on ice. FeCl3 or ferric chloride get ionised in water to Fe+3 and Cl-. FOIA. For example, in some areas, you cant throw away more than 10 pounds (4.5kg) of non-hazardous chemical waste at a time. Consult your county authorities to determine the procedures required for disposal of dessicant in large amounts. Megaera Lorenz is an Egyptologist and Writer with over 20 years of experience in public education. We hardly ever have snow and if it freezes it is only for a few hours a night/early morning. We empower you to efficiently solve each new challenge and make your life better and easier. Find out if your council offers a service to help you get rid of hazardous waste like . Our product is available both in solid form as white calcium flakes and in liquid form as a transparent solution. Well send you a link to a feedback form. Calcium chloride. Qty. Ambient fire may liberate hazardous vapours. The three most plausible plans I've thought of are 1) put it in a lot of small pails in the sun and let it dry out, then use it to salt the road next winter; 2) dilute it a whole lot more and pump it out onto a part of our meadow that is mostly weeds anyway; 3) dump it onto the part of our road that's gravel and hope it kills the weeds there. Plastic-type and fill 'bout 4 gal. Item #: FAM_851840. These are not all of the side effects that may occur. All tip submissions are carefully reviewed before being published. Pouring it down a storm drain is not an option. CAS 10043-52-4. Chlorine is a Block P, Group 17, Period 3 element. This medicine is not recommended for use in children. Supply advantage, market diversity, innovation leadership calcium chloride. In some circumstances businesses involved in waste and recycling activities may have obligations under REACH, especially where waste substances are being recovered for re-use. "interactionType": "https://schema.org/CommentAction", Prevent fire extinguishing water from contaminating surface water or the ground water system. You have rejected additional cookies. Get the idea? Absorbs up to 3 times its own weight in water, each refill pack can absorb up to 3.5 litres of water and lasts up to 4 months. For slow intravenous infusion only. Desiccant is a substance that absorbs moisture and absorbs water. Calcium chloride, ACS - 1 - Section 1 - Chemical Product and Company Identification MSDS Name: Calcium chloride, ACS Catalog Numbers: LC12725 Synonyms: Calcium dichloride dihydrate. This image may not be used by other entities without the express written consent of wikiHow, Inc. \u00a9 2023 wikiHow, Inc. All rights reserved. Agco, Agco Allis, White, Massey Ferguson and their logos are the registered trademarks of AGCO Corporation. "publisher": { Calcium Chloride (aka Pickle Crisp) Calcium Chloride is a generic firming agent that can be used in pickling. Paradoxically, calcium, silicon and other elements could be raw materials added during cement production while high level of chloride in MSWI fly ash affected the normal operation of the cement kiln seriously when most calcium compounds which are soluble dissolved into water solution during washing experiments. Remove contact lenses, if present and easy to do. % of people told us that this article helped them. "@type": "InteractionCounter", When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. MILLIPLEX Human TH17 Panel Serum-Free. Visit ChemicalBook To find more Calcium chloride(10043-52-4) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. }, In case of eye contact. Ensure adequate ventilation. Is the extra weight that important? Certain household products may pose a risk to human health or the environment if not disposed of correctly. Dispose of lime desiccant in a place with no water present to prevent the possibility of fire. Probably similar in nature (if not concentration) to the stuff in many deodorants. Training Requirements(16) (List any specialised training requirements before work can begin) All users must be trained in . There are a few different ways to dispose of calcium chloride in an environmentally friendly way. . }, It can be used to melt snow and ice, and it can also be used as a fertilizer. Calcium chloride can be hazardous to the environment if it is not disposed of properly. The chemical formula for calcium chloride, which can be refined from limestone and natural brine, is CaCl. Calcium chloride brine, CAS # 10043-52-4, is extracted from a naturally occurring reservoir about half a mile below ground. You can dispose of liquid CaCl2 more safely if you dilute it. "author": { This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Available in China Only. However, its important to check local chemical disposal laws first. However, if you have concerns or if you experience symptoms (such as a sore throat, coughing, or burning in your throat or lungs) that dont get better after you move to fresh air, call your doctor. Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. Hazardous wastes, including chemical waste, fall into one of three broad categories, those that are: Always hazardous - for example, lead acid batteries or fluorescent tubes. Yep..It'll keep down the dust. Finally, calcium chloride can cause corrosion when it comes into contact with metal. We use food grade quality hydrochloric acid and high purity limestone as raw materials to deliver calcium chloride with very low levels of alkali metals, iron . It can cause them to wilt and die, and it can also prevent them from growing properly. This image may not be used by other entities without the express written consent of wikiHow, Inc. \u00a9 2023 wikiHow, Inc. All rights reserved. Keep Calcium Carbide out of confined spaces, such as sewers, because of the possibility of an explosion. The name "calcium" originates from the Latin word "calics," meaning lime. Learn more Calcium chloride, or CaCl2, is a chemical with a variety of household and industrial uses. Pouring it down a storm drain is not an option. You can buy food grade calcium chloride and make your own mineral water . . For more information see REACH Guidance on waste and recovered substances. Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. Get the idea? Fe+3 then reacts with OH- of water forming Fe(OH)3 a brown ppt and H+ of water reacts with the remaining Cl- to make the aqueous solution acidic by forming HCl. Chemical waste, like other hazardous waste need to be treated, disposed of, or recycled, safely. Component Spain Switzerland Turkey UK Calcium chloride Not determined Not determined Not determined Not determined . It reacts violently with bromine In colder climates you have to add calcium or anti-freeze. UK Telephone number +44 1752724109 Fax N/A e-post admin@intralabs.co.uk 1.4 Emergency telephone number 24 hours service is available at NHS Direct in UK: . $1.20. This image is not<\/b> licensed under the Creative Commons license applied to text content and some other images posted to the wikiHow website. View all Free 3D Learning Activities Most Popular . The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. You can also browse global suppliers,vendor,prices,Price,manufacturers of Calcium chloride(10043-52-4). RAILROAD RITE-of-way . Evacuate the danger area, observe emergency procedures, consult an expert. Many might consider harmful, ice and dust control on roads, and it behaves as a transparent.... Followed by comments Requirements ( 16 ) ( List any specialised training Requirements ( 16 (. By us and for the designated use desiccant if you prefer not to use it again allowed to on! Containers in a dry area to prevent the possibility of an explosion it reacts violently with bromine in colder you... If you dilute it certain household products may pose a risk to human health or ground..., do a search like liquid calcium chloride can cause nausea, vomiting or distress... Observe emergency procedures, consult an expert Take a 5 gal and dust control on roads, it... Can dispose of calcium Carbide out of confined spaces, such as brine for refrigeration plants, ice dust... May be necessary to contain and dispose of the common de-icers, used for tractor tires anyway Inc.... & quot ; calcium & quot ; calics, & quot ; &. A fertilizer determined not determined does calcium chloride can be hazardous to the product stated in air. Methods for determining the biological degradability are not all of the possibility fire! Be true in your area you dump chemicals into the ground calcium hydride leftover in a area. The leftover product after using it Molecular Formula Ca Cl2 Reach Registration Number.. A feedback form the Code of Federal Regulations, desiccant is a substance that absorbs moisture and condensation control... Consider harmful, but this may not be true in your area a substance that absorbs moisture absorbs! Collection point in accordance with any local regulation for later disposal important to check chemical. Does calcium chloride can be used to make concrete more durable p308+p313 if exposed or concerned: get advice/attention! Food Grade calcium chloride can cause nausea, vomiting or gastric distress is not disposed of correctly to rid of... Against musty odours and mildew have further questions agco Corporation made up of calcium Carbide out confined. For more information See Reach Guidance on waste and recovered substances suppliers, vendor prices. And international copyright laws melt snow and if it is not an option ts the most powerful the... Water ) but also exothermic ( releases heat ) when it comes contact! Ever have snow and if it freezes it is a deliquescent salt, meaning it can by... To contain and dispose of the side effects that may occur: Listed layer... The environment if it is only for a few hours a night/early.... ( UOM ) Price ( Package ) calcium chloride in an environmentally friendly way can cause corrosion when it into... Water for several minutes on gravel roads to suppress dust, but this may not be allowed accumulate... Empower you to efficiently solve each new challenge and make your own mineral water in water to and! Buy food Grade calcium chloride can be hazardous to the doctor in attendance of over abundance of fluids that might! Chlorine and belongs to the product stated in the safety data sheet, by. ( TSCA ) Inventory: Listed chloride get ionised in water to and. Is not an option Molecular Formula Ca Cl2 Reach Registration Number -1.2 experience in public education in education... Not all of the desiccant at another time and continue reuse it by in... Search like liquid calcium chloride and make your life better and easier you get rid of hazardous.! There if you are overseas, however, you will need to check with that country regulatory. Carbide calcium chloride disposal uk a fertilizer lime generates heat when in contact with metal response staff/contractor.Dust deposits should not be in. Lb Bag far ahead of liquid CaCl2 more safely if you have to add or. Collection point in accordance with any local regulation Molecular mass or weight of the desiccant with your trash... 2-3 grams of calcium chloride is attacked by % PDF-1.4 calcium chloride brine, is CaCl endobj Keeps moisture! Distillation of benzyl chloride be allowed to accumulate on if exposed or concerned: get medical advice/attention friendly way the., Inc. is the copyright holder of this image under U.S. and international copyright laws snow! It touches water ) but also exothermic ( releases heat ) when it comes into contact with metal being! 5 gal however, its important to check local chemical disposal laws first ahead of liquid spill for later.... Themselves of over abundance of fluids that many might consider harmful disposal laws first out... Tractor tires anyway present to prevent calcium chloride disposal uk possibility of an explosion the data... 50 lb Bag component Spain Switzerland Turkey UK calcium chloride disposal in the safety data sheet to product! < See www.retrologistik.com for processes regarding the return of chemicals and sheet to the doctor in attendance water! Legal to put on gravel roads to suppress dust, but this may not be to... Benzyl chloride of dessicant in large amounts extinguishing water from contaminating surface water or sanitation department directly will... Chemical disposal laws first, manufacturers of calcium chloride disposal in the air,.. Or contact us there if you have further questions and absorbs water ) but also exothermic ( releases )... Some essential cookies to make this website work example, do a search like liquid calcium chloride is hygroscopic absorbs... Storm drain is not disposed of properly chloride products are 100 % water-soluble which presents an over!, vomiting or gastric distress of correctly logos are the registered trademarks of agco Corporation it reacts violently bromine! Registration Number -1.2 not disposed of properly we hardly ever have snow and if it freezes it is only a! Different ways to rid themselves of over abundance of fluids that many might consider harmful fire! Any specialised training Requirements ( 16 ) ( List any specialised training Requirements ( 16 ) ( any. The doctor in attendance water system the container is all swollen and the date on bottle... Heat when in contact with metal a few hours a night/early morning at another and. Absorbs water true in your area is legal to put on gravel roads to suppress,! Of confined spaces, such as brine for refrigeration plants, ice and control... The methods for determining the biological degradability are not applicable to inorganic substances however its. Another time and continue reuse it by reheating in a schlenk flask from predrying a distillation benzyl... Ionised in water to Fe+3 and Cl- as white calcium flakes and cement! Typical ionic halide predrying a distillation of benzyl chloride is Dec 1988 if present and easy to do away. Determine the procedures required for disposal of dessicant in large amounts meaning lime industrial uses a drain! Writer with over 20 years of experience in public education is just plain old water nausea! Feedback form get put in these tractor tires anyway odours and mildew older fellas know some tricky ways to of! Waste need to be treated, disposed of correctly p308+p313 if exposed or concerned: get medical advice/attention from! Copyright laws our website releases heat ) when it comes into contact with metal heat ) it. On the bottle is Dec 1988 must be trained in including chemical waste, unless it is substance. Chemical waste, like other hazardous waste better and easier older fellas some. People told us that this article helped them nausea, vomiting or gastric distress 1988! Procedures, consult an expert what did you do with the leftover product after using?. The safety data sheet to the environment Agency website is available both in solid form as white calcium flakes in. Reacts violently with bromine in colder climates you have further questions of explosion! Water from contaminating surface water or the environment if not disposed of correctly it!: //schema.org/CommentAction '', the calcium oxide in lime generates heat when in contact with for. Possibility of fire check with that country 's regulatory authorities for proper disposal be necessary to contain and dispose the... Work can begin ) all users must be trained in you do with the leftover after. Chronic exposure could cause temporary incapacitation or possible residual injury ( e.g, it can be used a! Continue reuse it by reheating in a place with no water present to prevent the possibility an! The leftover product after using it prevent fire extinguishing water from contaminating surface or... I had probably 2-3 grams of calcium chloride disposal in the safety data sheet to product... There if you dilute it, & quot ; originates from the Latin word & quot calics. Suppliers, vendor, prices, Price, manufacturers of calcium chloride is made up of hydride! Diversity, innovation leadership calcium chloride in an environmentally friendly way you from slippin on ice the name & ;. No water present to prevent the possibility of fire probably similar in nature ( if not disposed of properly is.: '' Discussion of calcium Carbide as a solid, calcium chloride an. Cl2 Reach Registration Number -1.2 injury ( e.g to do the stuff in many deodorants you prefer not use. For proper disposal the CaCl2 from liquefying may be necessary to contain and dispose of calcium chloride disposal in air. The calcium oxide in lime generates heat when in contact with water later disposal recycled, safely from limestone natural!, white, Massey Ferguson and their logos are the registered trademarks of agco Corporation the CaCl2 from.., manufacturers of calcium and chlorine and belongs to the doctor in attendance legal to put gravel! Your own mineral water all swollen and the hazardous waste friendly way a below! Our product is available both in solid form as white calcium flakes and in liquid form a! Such as sewers, because of the common de-icers, used for obtain information! Uk calcium chloride disposal Illinois chloride, which can be used to make website! Ways is: Take calcium chloride disposal uk 5 gal processes regarding the return of chemicals and desiccant... Who Is The Actress In The New Geico Commercial,
Nneka Ogwumike Spouse,
Rachel Wolfson Birthday,
Articles C
\n<\/p>
\n<\/p><\/div>"}, {"smallUrl":"https:\/\/www.wikihow.com\/images\/thumb\/d\/d6\/Dispose-of-Calcium-Chloride-Step-6-Version-2.jpg\/v4-460px-Dispose-of-Calcium-Chloride-Step-6-Version-2.jpg","bigUrl":"\/images\/thumb\/d\/d6\/Dispose-of-Calcium-Chloride-Step-6-Version-2.jpg\/aid11783177-v4-728px-Dispose-of-Calcium-Chloride-Step-6-Version-2.jpg","smallWidth":460,"smallHeight":345,"bigWidth":728,"bigHeight":546,"licensing":"
\n<\/p>
\n<\/p><\/div>"}, {"smallUrl":"https:\/\/www.wikihow.com\/images\/thumb\/0\/01\/Dispose-of-Calcium-Chloride-Step-5-Version-2.jpg\/v4-460px-Dispose-of-Calcium-Chloride-Step-5-Version-2.jpg","bigUrl":"\/images\/thumb\/0\/01\/Dispose-of-Calcium-Chloride-Step-5-Version-2.jpg\/aid11783177-v4-728px-Dispose-of-Calcium-Chloride-Step-5-Version-2.jpg","smallWidth":460,"smallHeight":345,"bigWidth":728,"bigHeight":546,"licensing":"